The necessity to produce modern composites with an acceptable impact resistance is an essential task in automobile and aerospace industry that needs to be satisfied. This capability is addressed by noteworthy energy absorption augmentation which is the most vital characteristic of such composite materials. In this paper, nanofibers are applied as interleaves to modify the delamination strength with a minimum rise in weight and thickness of the high-modulus polypropylene/epoxy composites. Nylon 6,6 nanofibers are produced by the electrospinning method. The distribution of nanofibers across the mats is examined by SEM. Innegra fabrics have been applied in composite layers production. The proper hand lay-up manufacturing of the laminates has been assured by the assistance of a hydraulic press. The energy absorption capacity at the onset of breakdown and impact resistance of the nanomodified and non-modified laminates were determined by quasi-static three-point flexural for the former and low-velocity impact tests for the latter. The obtained results were compared. The results showed a 6.2 and 16.9% increase in the energy absorption capacity of nanomodified laminates in quasi-static three-point flexural test and low-velocity impact tests, respectively. In addition, low-velocity impact tests revealed 16 and 26% improvement in maximum load capacity.