Compared to commonly applied wet and dry heating procedures, a combination of electrospinning and heat treatment can facilitate glycation of proteins with reducing polysaccharides. This study investigates how the amount of reducing carbonyl groups (i.e. dextrose equivalent, DE) of different maltodextrins influences electrospinnability and subsequent glycation in blends with pea protein isolate (PPI). In the first step of the study, maltodextrin-PPI dispersions were electrospun. The concentrations of PPI and maltodextrin DE 2 were kept constant in the aqueous spinning dispersion. The addition of 0.05 or 0.1 g/mL maltodextrin DE 12 or 21 slightly affected the electrical conductivity and dynamic viscosity of the spinning dispersions, however, fiber production rate and morphology were dominated by the presence of maltodextrin DE 2 (0.8 g/mL). In the second step of the study, fibers were heated (60 degrees C, 75% rel. Humidity, 0-24 h). SDS-PAGE analysis and the measurement of free amino groups confirmed the covalent attachment of maltodextrin carbonyl groups to free amino groups of PPI. The fastest glycation and the lowest relative amount of free amino groups (49.70 +/- 6.54%) after 24 h heating was measured for the fibers with the highest amount of reducing carbonyl groups. The fibers with the lowest amount of reducing carbonyl groups showed no significant (p < 0.05) decrease of free amino groups after heat treatment. The results suggest that within the boundaries of electrospinnability, the degree of glycation can be adjusted by varying the amount of reducing carbonyl groups in the fibers.