The effect of electrospinning operational parameters on the morphology, surface roughness, and wettability of different compositions of electrospun polystyrene (PS)-aluminum oxide (Al2O3) nanocomposite coatings was investigated using different techniques. For example, a scanning electron microscope (SEM) coupled with an energy dispersive X-ray (EDX) unit, a Fourier transform infrared (FTIR) spectrometer, an atomic force microscope (AFM), and water contact angle (WCA), and contact angle hysteresis (CAH) measurements using the sessile droplet method, were used. The latter used 4 mu L of distilled water at room temperature. PS/Al2O3 nanocomposite coatings exhibited different morphologies, such as beaded fibers and microfibers, depending on the concentration ratio between the PS and Al2O3 nanoparticles and the operational parameters of the electrospinning process. The optimum conditions to produce a nanocomposite coating with the highest roughness and superhydrophobic properties (155 degrees +/- 1.9 degrees for WCA and 3 degrees +/- 4.2 degrees for CAH) are 2.5 and 0.25 wt % of PS and Al2O3, respectively, 25 kV for the applied potential and 1.5 mL.h(-1) for the solution flow rate at 35 degrees C. The corrosion resistance of the as-prepared coatings was investigated using the electrochemical impedance spectroscopy (EIS) technique. The results have revealed that the highly porous superhydrophobic nanocomposite coatings (SHCs) possess a superior corrosion resistance that is higher than the uncoated Al alloy by three orders of magnitude.