Nowadays, encapsulated dyes in a polymeric matrix have opened up new perspectives in many applications such as filtration of subatomic particles, composite reinforcement, multifunctional membranes, tissue engineering scaffolds, wound dressing, coatings, medical purposes as well as sensors. In the presented work, we report on electrospinning neat peryelene dianhydride based thermoplastic elastomers. Perylene-3,4,9,10-tetracarboxylic dianhydride (PDA) is encapsulated into cellulose acetate (CA) electrospun fibers, which was prepared from 12% cellulose acetate solution, at 20 kV with a distance of 10 cm. The flow rate was 0.2 ml.h(-1). These water repellent nanofibrous coatings are anticipated to serve as hydrophobic coatings. Scanning electron microscope is used to study the properties of the electrospun PDA-CA nanofibers.