The diameter of the nanofiber and area of deposition are the two most important properties that define the morphology of nanofiber webs. This study aims at exploring the effect of electrospinning parameters on the area of deposition of nanofibers. The area of deposition of the nanofiber web was found to be dependent on the process parameters such as needle to collector distance, collector voltage, and flow rate as well. Based on the observations, a simple model has been proposed to explain the behavior of electrospinning in a bipolar configuration.