Polymethylacrylate (PMA) nanofibers membranes are fabricated by electrospinning technique and applied to the polymer matrix in quasi-solid-state electrolytes for dye sensitized solar cells (DSSCs). There is no previous studies reporting the production of PMA nanofibers. The electrospinning parameters such as polymer concentration, applied voltage, feed rate, tip to collector distance and solvent were optimized. Electrospun PMA fibrous membrane with average fiber diameter of 350 nm was prepared from a 10 wt% solution of PMA in a mixture of acetone/N,N-dimethylacetamide (6:4 v/v) at an applied voltage of 20 kV. It was then activated by immersing it in 0.5 M LiI, 0.05 M I-2, and 0.5 M 4-tert-butylpyridine in 3-methoxyproponitrile to obtain the corresponding membrane electrolyte with an ionic conductivity of 2.4 x 10(-3) S cm(-1) at 25 degrees C. Dye sensitized solar cells (DSSCs) employing the quasi solid-state electrolyte have an open-circuit voltage (V-oc) of 0.65 V and a short circuit current (J(sc)) of 6.5 mA cm(-2) and photoelectric energy conversion efficiency (eta) of 1.4% at an incident light intensity of 100 mW cm(-2). (C) 2016 Faculty of Engineering, Alexandria University. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).