ZnO nanomaterials with different shapes were synthesized, characterized and tested in the selective monitoring of low concentration of CO and NO2 in air. ZnO nanoparticles (NPs) and nanofibers (NFs) were synthesized by a modified sol-gel method in supercritical conditions and electrospinning technique, respectively. CO and NO2 sensing tests have demonstrated that the annealing temperature and shape of zinc oxide nanomaterials are the key factors in modulating the electrical and sensing properties. Specifically, ZnO NPs annealed at high temperature (700 degrees C) have been found sensitive to CO, while they displayed negligible response to NO2. The opposite behavior has been registered for the one-dimensional ZnO NFs annealed at medium temperature (400 degrees C). Due to their adaptable sensitivity/selectivity characteristics, the developed sensors show promising applications in dual air quality control systems for closed ambient such as automotive cabin, parking garage and tunnels.