We investigate electrical and dielectric properties of cadmium titanate (CdTiO3) nanofiber mats prepared by electrospinning. The nanofibers were polycrystalline having diameter similar to 50 nm-200 nm, average length similar to 100 mu m and crystallite size similar to 25 nm. Alternating current impedance measurements were carried out from 318 K - 498 K. The frequency of ac signal was varied from 2 - 10(5) Hz. The complex impedance plots revealed two depressed semicircular arcs indicating the bulk and interface contribution to overall electrical behavior of nanofiber mats. The bulk resistance was found to increase with decrease in temperature exhibiting typical semiconductor like behavior. The modulus analysis shows the non-Debye type conductivity relaxation in nanofiber mats. The ac conductivity spectrum obeyed the Jonscher power law. Analysis of frequency dependent ac conductivity revealed presence of the correlated barrier hopping (CBH) in nanofiber mats over the entire temperature range. Copyright 2013 Author(s). This article is distributed under a Creative Commons Attribution 3.0 Unported License. [http://dx.doi.org/10.1063/1.4799756]