La-doped NiO nanofibers were synthesized by the electrospinning method. The X-ray diffraction (XRD) pattern showed that La doping does not change the crystal structure up to the doping ratio of La/Ni= 1.5%. Electrochemical properties of La-doped NiO nanofibers were investigated using cyclic voltammetry and galvanostatic charge/discharge. The results showed that the La doping can enhance the charge/discharge specific capacitance and electrochemical stability of the NiO nanofibers. Especially, the sample with doping ratio of La/Ni= 1.5% could reach a discharge specific capacitance of 94.85 F g(-1) at a constant current density of 5 mA cm(-2). (c) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.