Electrospinning is recognized as a simple and easy method to produce fibers with nanoscale diameters. However, the methods for controlling the shape, structure, and uniformity of electrospun fibers have not yet been fully investigated. In this research, the electrospinning jet behavior, corresponding nanofiber deposition, and average fiber diameter are examined for various nozzle diameters. Fluctuations in the sequence of drop growing, electrospinning, and/or termination of electrospinning are analyzed. We propose two different fluctuations according to nozzle diameter. The multi-jet ejections, that are closely related to the amount of nanoweb deposition and the deposition pattern, are explored.