Superhydrophobic-superoleophilic fibrous polymethyl methacrylate (PMMA) membranes were prepared by electrospinning technique. The membranes exhibited a high water contact angle up to 153.9 degrees. and nearly zero oil contact angle. This super wettability property is attributed to hierarchical macro- and nanostructure on surface of PMMA membrane and can be conveniently tuned by adjusting the weight ratio of binary solvent of N,N-dimethylacetamide and acetone. Resultant fibrous PMMA membranes with superhydrophobic-superoleophilic property can be used in water treatment. This facile one-step strategy shows an alternative approach to produce special wettability surface and will benefit this material. (C) 2015 Elsevier B.V. All rights reserved.