Silver-impregnated TiO2/nylon-6 nanocomposite mats exhibit excellent characteristics as a filter media with good photocatalytic and antibacterial properties and durability for repeated use. Silver nanoparticles (NPs) were successfully embedded in electrospun TiO2/nylon-6 composite nanofibers through the photocatalytic reduction of silver nitrate solution under UV-light irradiation. TiO2 NPs present in nylon-6 solution were able to cause the formation of a high aspect ratio spider-wave-like structure during electro-spinning and facilitated the UV photoreduction of AgNO3 to Ag. TEM images, UV-visible and XRD spectra confirmed that monodisperse Ag NPs (approximately 4 nm in size) were deposited selectively upon the TiO2 NPs of the prepared nanocomposite mat. The antibacterial property of a TiO2/nylon-6 composite mat loaded with Ag NPs was tested against Escherichia coli, and the photoactive property was tested against methylene blue. All of the results showed that TiO2/nylon-6 nanocomposite mats loaded with Ag NPs are more effective than composite mats without Ag NPs. The prepared material has potential as an economically friendly photocatalyst and water filter media because it allows the NPs to be reused. (C) 2011 Elsevier B.V. All rights reserved.