Organic polymer electrolytes attracted a great deal of attention and research in the field of energy conversion and energy storage due to their benefits such as appreciable ionic conductivity and transference number, improved mechanical strength, thermal stability, and better interaction with the electrodes. In this study, a polymer electrolyte was synthesized from poly(vinyl alcohol) (PVA) by electro-spinning technique followed by soaking in a series of deep eutectic solvents (DESs) to enhance the electrical conductivity of the product. The result was a very thin, nonwoven membrane. The produced membranes showed appreciable improvement in electrical conductivity from 2.78 x 10(-6) to 2.27 x 10(-2) S/cm after soaking in DES2. The observed improvement in electrical properties opens the possibility for the PVA membranes to find their applications in-batteries, storage cells, flexible thermoelectric devices, sensors, and solar cells .