Nanofibers of poly(lactic acid) (PLA) blended with polyaniline (PANi) were fabricated via electrospinning at much lower PLA concentrations (similar to 1wt%) in CHCl3 than reported before using a more efficient technique of preparing the solutions. The polymer nanofibers had diameters in the range 10 nm-300 nm. Nanofibers prepared with a 3 wt% PLA/PANi solution were conducting and were used to fabricate a diode which was electrically characterized and exhibited a low turn-on voltage and a rectification ratio of 500. The device characteristics were analyzed using the standard thermionic emission model of a Schottky junction and yielded an ideality factor of 1.6 and a barrier height of 0.49 eV. Using a simple circuit, the diode was able to rectify a low frequency alternating current signal with an efficiency of 10%. The ability to engineer insulating PLA into nanofibers that are electro-active extends the range of applications of this biocompatible and biodegradable polyester to include electronic devices that have reduced toxicity. (C) 2014 Elsevier Ltd. All rights reserved.