Pt/SnO2 nanofibers were synthesized via electrospinning. The unique electrochemical properties were in evidence based on the activity that allowed a hydrogen oxidation reaction and inhibit an oxygen reduction reaction. A high electrochemically active surface area value of 81.17 m(2)/g-Pt was achieved with ultra-low Pt loading (4.03 wt.%). The kinetics of a hydrogen oxidation reaction was investigated using a linear sweep voltammetry technique under a hydrogen atmosphere. A diffusion-limited current was achieved at 0.07 V and was stable at a high potential. This preparation technique shows great promise for the design of anode electrocatalyst material for fuel cells. (C) 2012 Elsevier B.V. All rights reserved.