Mesoporous carbon nanofibers (CNFs) were prepared by a sol-gel/electrospinning process using phenolic resin precursor as carbon source and triblock copolymer Pluronic F127 as template. The final CNFs were obtained after carbonization of as-spun nanofibers and removal of SiO2. Three samples (C-1, C-2, and C-3) with different pore textures were synthesized. The CNF structures were characterized by scanning and transmission electron microscopy, and N-2 adsorption-desorption measurements, demonstrating that the samples consisted of nanofibers with mesopores and the mesopore volumes depended on the amount of tetraethyl orthosilicate in the spinnable sols. According to thermogravimetric analysis, the CNF yields of 2.57%, 2.78%, and 2.13% from the spinnable sols for sample C-1, C-2, and C-3 were obtained, respectively. The mesoporous CNFs were used as highly efficient adsorbents for large dye molecules. The relationship between the pore textures and adsorption properties was studied. It is suggested that the adsorption of different dyes depend on an appropriate pore size distribution in addition to surface area. However, the adsorption capacity of the regenerated adsorbents gradually decreased with the number of regeneration cycles. The adsorption of acid red 1 could reach 186 mg g(-1) for C-3 after seven regeneration cycles. Furthermore, the mechanical strength of CNFs needs improvement. (C) 2012 Elsevier Ltd. All rights reserved.