High-voltage LiMn1.5Ni0.5O4 spinel with one-dimensional (1D) hollow and porous architecture is fabricated via a facile single-spinneret electrospinning technique. The hierarchical porous LiMn1.5Ni0.5O4 hollow nanofibers possess similar to 200 nm in diameter and tens of micrometers in length, as well as a specific surface area as high as 43.2 m(2) g(-1). When served as Li-ion battery cathodes, the as-fabricated material delivers high specific capacities of 135 and 98 mAh g(-1) at 0.68 C and 20.4 C, respectively. Under a long-term cycling operation at 6.8 C, the cathode sustains good capacity retention of 90% after 1000 cycles. The outstanding electrochemical performance can be attributed to the porous 1D hollow nanostructure that can enlarge effective electrode/electrolyte contact areas, shorten electron/ion transport distance and accommodate volume change. (C) 2017 Elsevier B.V. All rights reserved.