We report herein a simple, low-cost and scalable fabrication of unique wheat grain-like textured TiO2/CuO composite nanofibers (NFs) by electrospinning. Unlike conventional surface coupling/loading of co-catalyst nanoparticles, incorporation of copper nanoparticles during the electrospinning of TiO2 NFs ensures good stability and recyclability due to resistance against nanoparticles leaching. Optimization of electrospun NFs shows that TiO2/CuO composite NFs with 2.5 wt% copper nanoparticles, annealed at 500 degrees C exhibit highly textured structure with enhanced photocatalytic H-2 generation of 16.8 times higher than that of bare TiO2 NFs. Furthermore, the electrospun TiO2/CuO composite NFs demonstrate favorable photodegradation activity. The ease of tuning morphology and its heterostructure composite as well as separation and recovery of the fibrous photocatalyst after photoreaction renders immense potential to remedy global environmental and energy issues. (C) 2014 Elsevier Ltd. All rights reserved.