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Electrospun Li3.9Cr0.3Ti4.8O12 nanofibers as anode material for high-rate and low-temperature lithium-ion batteries
2019/11/27 21:19:10 Zou, H. L., H. F. Xiang, X. Liang, X. Y. Feng, S. Cheng, Y. Jin and C. H. Chen
Li3.9Cr0.3Ti4.8O12 nanofibers with one-dimensional (1D) morphology and excellent electrical conductivity are prepared via a facile electrospinning technique. The as-prepared Li3.9Cr0.3Ti4.8O12 nanofibers exhibit excellent lithium storage performance with superior rate capability and low-temperature performance: 140 mAh g(-1) at 10 C and 91 mAh g(-1) at 50 C rates at room temperature, 100 mAh g(-1) at 1 C rate at 20 degrees C. The superior electrochemical performance of Li-3.9Cr0.3Ti4.8O12 nanofibers is attributed to the 1D nano-architectures composed of nanocrystals and the reduced grain size in Li3.9Cr0.3Ti4.8O12, both of which facilitate the Li+ ion transport. The Li3.9Cr0.3Ti4.8O12 nanofibers also have a high Ti3+ concentration and an in-situ surface coating layer of Li2CrO4, which could enhance intraparticle and interparticle electronic conductivities of Li3.9Cr0.3Ti4.8O12 grains, respectively. (C) 2017 Elsevier B.V. All rights reserved.
  • Journal: Journal Of Alloys And Compounds
  • Volume: 701
  • Issue:
  • Pages: 99-106
  • ISSN: 0925-8388
  • DOI: 10.1016/j.jallcom.2017.01.067
  • Year: 2017
  • Number:
  • Type:
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